This data has not passed through its final quality assurance process
This data has not passed through its final quality assurance process
This data has not passed through its final quality assurance process
For access to data beyond the most recent 30-day period, contact Argos:
PorterRanch@argos-sci.co.za
+1 (503) 421-0228
What is it?
Benzene is a colorless, highly flammable liquid with a sweet gasoline odor.
Why measure it?
Benzene is a cancer-causing chemical and is second only to diesel exhaust as a cancer-causing pollutant in the LA Basin. While the bulk of benzene in the air comes from vehicle exhaust, it is important to measure the concentration in ambient air to identify and control emissions from industrial sources including refineries.
How might it affect my health?
Short-term inhalation of high levels of benzene can cause dizziness, lightheadedness, and headaches as well as lung irritation. The long-term effects of benzene exposure are related to anemia and effects on the bone marrow. Benzene is classified as a cancer-causing chemical in humans based on workers with long-term occupational exposure as well as on animal studies.
What concentration of benzene is typically found in air in the South Coast Air Basin?
The average concentration of benzene found in the LA Basin is 0.40 ppb, with concentrations ranging from 0.02 to 1.77 ppb.
The California EPA's Office of Environmental Health Hazard Assessment (OEHHA) has information on benzene. In addition, the CDC has ToxFAQs fact sheets for benzene.
What is it?
Toluene is a colorless liquid that smells like paint thinner.
Why measure it?
Like the other components of BTEX (benzene, ethylbenzene and xylene), toluene is a major contributor to ozone formation in the LA air basin.
How might it affect my health?
Exposure to low to moderate levels of toluene can irritate the nose, throat and eyes, lungs, and cause headaches. Long-term daily breathing of toluene by workers has been associated with hearing and color vision loss. Toluene is the ingredient in airplane glue and paints that led to wide-spread abuse when inhaled causing nervous system damage.
What concentration of toluene is typically found in air in the South Coast Air Basin?
Toluene concentrations typically equal 1.11 ppb on average in the LA Basin. Concentrations ranged from 0.1 to 6.15 ppb.
The California EPA's Office of Environmental Health Hazard Assessment (OEHHA) has information on toluene. In addition, the CDC has ToxFAQs fact sheets for toluene.
What is it?
Ethylbenzene is a colorless liquid that smells like gasoline. It evaporates at room temperature and burns easily.
Why measure it?
Like the other components of BTEX (benzene, toluene and xylene), ethylbenzene contributes to the formation of ozone.
How might it affect my health?
Breathing very high levels of ethylbenzene can cause throat and eye irritation and dizziness. Breathing lower levels over long periods of time causes hearing and kidney damage in animals. The World Health Organization has identified ethylbenzene as a possible human carcinogen based on animal studies.
What concentration of ethylbenzene is typically found in air in the South Coast Air Basin?
The average concentration of ethylbenzene in the LA Basin is 0.23 ppb. The maximum concentration reported equaled 4.75 ppb.
The CDC has ToxFAQs fact sheets for ethylbenzene.
What is it?
Xylene is a colorless, flammable liquid with a sweet odor.
Why measure it?
Like the other components of BTEX (benzene, toluene and ethylbenzene), xylene is a major contributor to ozone formation in the LA air basin.
How might it affect my health?
Exposure to high levels of xylene for short periods of time can irritate the eyes, nose, throat, or skin. Both short- and long-term exposure to high levels of xylene may cause effects on the nervous system such as headaches, dizziness, confusion, and lack of muscle coordination.
What concentration of xylene is typically found in air in the South Coast Air Basin?
There are three forms of xylene which are measured in the LA Basin air and all function similarly. Meta- and para-xylene concentrations were on average 0.77 ppb in the LA Basin, while ortho-xylene concentrations were 0.19 ppb on average.
The California EPA's Office of Environmental Health Hazard Assessment (OEHHA) has information on xylenes. In addition, the CDC has ToxFAQs fact sheets for xylenes.
What is it?
Methane is a colorless and odorless gas.
Why measure it?
Methane is flammable in high concentrations, between 5% and 15% (equivalent to 50,000 to 150,000 ppm). Measurements conducted by South Coast AQMD staff and other agencies in the Porter Ranch community show that methane levels are far below the concentrations where flammability would be a concern.
How might it affect my health?
Methane is considered to be biologically inert, but can cause health effects when levels are high enough to displace oxygen in the air, which can pose a suffocation hazard. However, this is generally only a concern in confined spaces (such as the inside of a tank), rather than in outdoor environments or typical indoor environments, where oxygen is readily available.
What concentration of methane is typically found in air in the South Coast Air Basin?
Methane is not considered an air toxic, as it is not on the California Toxic Air Contaminants list, nor the California Proposition 65 list, nor is it on the U.S. EPA Hazardous Air Pollutants list. However, methane is considered a climate pollutant (i.e. greenhouse gas), and is primarily regulated through state and federal regulations.
The CDC has ToxFAQs fact sheets for methane.
The UV DOAS (Ultraviolet Differential Optical Absorption Spectroscopy) analyzers detect gases on a real-time basis using beams of ultraviolet light. The system identifies gases by examining the wavelengths of UV light that have been absorbed by the gases present in the light beam. The instruments have a spectral library of gases covering the concentration range of the analyzer. It also includes libraries of potential interfering gases such as oxygen and ozone. Data from each UV instrument are averaged at approximate five-minute intervals.
The TDL (Tunable Diode Laser) analyzers detect methane gas on a real-time basis using beams of infrared light. If methane gas is present in the air, it will absorb at certain known wavelengths of the light. TDL air monitoring systems use a very narrow band of wavelengths to detect gases and thus are typically designed to detect only a single gas such as methane.
Point Monitoring TDL
Point monitoring in air quality assessment involves measuring pollutant concentrations at specific, strategically chosen locations using specialized equipment. This method provides detailed, localized air quality data for environmental impact assessments. While offering precise information at certain points, it does not cover large areas, often necessitating complementary methods like fence-line monitoring for broader analysis. The data from point monitoring is vital for the analysis of air quality and determining potential pollution sources.
Open-Path TDL
Open-path monitoring in air quality assessment employs light-based technologies to measure pollutant concentrations over extended distances. This method is effective for detecting gases such as benzene, and various volatile organic compounds. Unlike point monitoring, which measures pollutants at a single location, open-path monitoring covers larger areas, offering a broader view of air pollution. It provides real-time data, averaging pollutant levels over the entire path, making it ideal for community fence-line monitoring. This approach is crucial for comprehensive environmental management and understanding air pollution dynamics on a larger scale.
Gas chromatographs (GCs) are fixed-point analyzers which record data in one-hour intervals. GCs are able to separate compounds in the gaseous phase in order to quantify them.
A system setup to continuously measure weather parameters such as wind speed, wind direction, temperature, humidity and barometric pressure. MET stations are particularly useful in pollutant source identification and the effect of weather events, such as fog or heavy winds, on the system performance.
Wind Speed and Wind Direction
Wind speed (or wind flow velocity) measures the movement of air in miles per hour (mph). Wind direction shows the direction from which the wind is blowing. For example, a west wind blows from the west to the east.
Parameter of Interest (Open-Path) | Sample Method | Data Acquisition | Configuration |
---|---|---|---|
Benzene | UV DOAS | Continuous, real-time | Open-path |
Ethylbenzene | UV DOAS | Continuous, real-time | Open-path |
Toluene | UV DOAS | Continuous, real-time | Open-path |
Xylene | UV DOAS | Continuous, real-time | Open-path |
Methane | TDL | Continuous, real-time | Open-path |
Parameter of Interest (Point) | Sample Method | Data Acquisition | Configuration |
---|---|---|---|
Benzene | GC | Semi-continuous | Point |
Ethylbenzene | GC | Semi-continuous | Point |
Toluene | GC | Semi-continuous | Point |
Xylene | GC | Semi-continuous | Point |
Methane | TDL | Continuous, real-time | Point |
Meteorological (MET) | MET specific sensors | Continuous, real-time | Point |
Micrograms per cubic meter (µg/m³) is a measure of how many micrograms are in a cubic meter of air.
The US Environmental Protection Agency (EPA) has information on micrograms per cubic meter.
Parts per billion (ppb): A part per billion is the unit of concentration measured. It is a ratio referring to the number of measured molecules of a target compound in one billion molecules of air. For example, a measure of 1 ppb benzene is one molecule of benzene in one billion molecules of air.
Parts per million (ppm): A part per million is the unit of concentration utilized. It signifies a ratio indicating the number of measured molecules in one million molecules of air. Similarly, a measure of 1 ppm benzene is one molecule of benzene in one million molecules of air.
The US Environmental Protection Agency (EPA) has information on ppb/ppm.
Below REL
Concentration levels below the REL are not expected to cause adverse health effects. When values at the 1-hour average are below the REL, they are labeled as "Below REL." The concentration gauge displays this as a green bar that fills according to the percentage of REL reached.
Above REL
Values at the 1-hour average are labeled "Above REL" when they meet or exceed the reference level. The concentration gauge displays an orange bar when the REL is reached or surpassed.
Pollutant | One Hour Acute Exposure |
---|---|
Benzene | 8 ppb |
Toluene | 1300 ppb |
Total Xylenes | 5142 ppb |
One hour acute concentration is the amount of time you need to be exposed to that concentration for one hour before even the most sensitive groups exhibit health impacts.
Note: There may be other levels associated with longer averaging times.
For more information on RELs, refer to the OEHHA website.
The Office of Environmental Health Hazard Assessment (OEHHA) is a California state agency responsible for evaluating health risks associated with environmental exposures. OEHHA's primary mission is to protect and enhance public health by providing scientific assessments of environmental contaminants, chemicals, and substances. The agency was established in 1991 and operates under the California Environmental Protection Agency.
Here are some of the key functions and activities of OEHHA:
OEHHA's work is crucial in ensuring safety by identifying and mitigating potential health hazards in the environment. The agency's assessments and recommendations help shape regulations and policies aimed at safeguarding public health and the environment in the state of California and can be used as a guide for elsewhere.
For more information, visit the OEHHA Environmental Topics page.
A brief overview of the potential health effects of the gases and compounds related to the Aliso Canyon leak are detailed below.
Gases
Air pollution from organic compounds can have significant adverse effects on public health. Organic compounds are pollutants, including benzene, toluene, ethylbenzene and xylene (BTEX) and methane, which are measured at Porter Ranch. Adverse public health effects are a particular concern to the sensitive population, including children, the elderly and people with pre-existing health conditions.
Methane
In the concentrations typically found in the atmosphere, methane does not present direct health risks to humans. However, in confined spaces or in very high concentrations, it can be an asphyxiant, displacing oxygen in the air.
Volatile Organic Compounds (VOCs)
The release included VOCs such as benzene, toluene, ethylbenzene, and xylenes (BTEX), some of which can cause health problems if inhaled. VOCs can cause symptoms like eye, nose, and throat irritation, headaches, loss of coordination, and nausea. Prolonged exposure may lead to more serious health issues like damage to the liver, kidneys, and central nervous system.
Mercaptans (Odorants)
Natural gas is odorless, so an odorant, typically a type of mercaptan, is added to make leaks detectable. Residents in the vicinity of the Aliso Canyon leak reported smelling a strong odor due to these odorants. Exposure can lead to symptoms like eye and respiratory irritation, nausea, and vomiting.
Benzene
This is a known carcinogen and was detected in the emissions from the leak. Long-term exposure to benzene can increase the risk of certain cancers, especially leukemia. Even short-term exposure can lead to symptoms like dizziness, tremors, irregular heartbeat, and even unconsciousness at high levels.
Many residents living near the Aliso Canyon facility reported various health symptoms during the leak, including headaches, nosebleeds, dizziness, respiratory problems, and nausea. It's important to note that while these symptoms can be associated with exposure to the gases and compounds mentioned, definitively linking them to the blowout requires comprehensive health studies such as the one currently being undertaken by the UCLA School of Public Health.
The Clean Air Act
The Clean Air Act, which was last amended in 1990, requires the US Environmental Protection Agency (EPA) to set National Ambient Air Quality Standards (NAAQS) for air pollutants considered to be harmful to public health and the environment. The Clean Air Act identifies two types of national ambient air quality standards.
Note: None of the NAAQS compounds are being measured in the PRCAMP.
The EPA
The EPA has set NAAQS for six principal pollutants, which are called "criteria" air pollutants. Periodically, the standards are reviewed and may be revised. The current standards are listed below. Units of measure for the standards are parts per million (ppm) by volume, parts per billion (ppb) by volume, and micrograms per cubic meter of air (µg/m³).
The South Coast Air Quality Management District
The South Coast Air Quality Management District (South Coast AQMD) is the local air pollution control agency for all of Orange County and major portions of Los Angeles, Riverside, and San Bernardino Counties. The South Coast AQMD enforces air pollution control at the local level throughout southern California. The South Coast AQMD collects data on current air quality, provides air quality forecasts, and analyzes trends in levels of pollutants. In addition, South Coast AQMD staff work on specific projects throughout southern California to reduce air pollution.
The detection limit, also known as the "minimum detection limit (MDL)," is the smallest concentration level that the equipment can measure with high accuracy. The three factors that make MDLs vary are compound, path length, and ambient conditions.
"Below detection limit (BDL)" means the concentration level is unknown to the instrument. Information about the equipment Argos Scientific, Inc. is using can be found in the "Resources" tab under "Instruments."
A 1 hour average is a data point produced from the data in the previous hour. Whereas, a 5 minute average is a data point from the previous 5 minutes of data collected.
The data displayed on this website is the raw data from the instruments in the field which are updated in near real-time. The data, as displayed, has not yet been through a rigorous quality control process required for the data to be considered final. However, a number of automated checks are done to provide a preliminary quality check. Data are considered preliminary for one quarter (90 days), at which point they are reviewed, finalized, and submitted to the South Coast AQMD.
The fence-line monitors send UV or infrared (IR) light beams across a path to a reflector which sends the light back to the source. When compounds in the air pass through the beam of light, some of the light is absorbed. The wavelength at which the light is absorbed and the amount of light absorbed determines which compounds are being detected and quantifies how much of it is in the air. The greater the absorption of light, the higher the concentration of that compound.
Note that open-path monitors cannot distinguish between a widely dispersed, low-concentration plume and a narrow, high-concentration plume. Rather, the monitors detect average concentrations across the entire distance from the source to the reflector.
Porter Ranch is located in Southern California several miles northeast of Los Angeles, California. Less than one mile north of Porter Ranch is Aliso Canyon's natural gas storage facility operated by SoCalGas. In October 2015, Well SS-25 at the facility ruptured, resulting in a 4-month-long natural gas leak. During the initial months of the leak, elevated levels of volatile organic compounds, mercaptans, and sulfides were detected in the Porter Ranch community.
This incident had a profound and devastating impact on the neighboring communities, resulting in acute symptoms such as severe nosebleeds, headaches, and nausea. In response to these health concerns, over 2,200 families within a five-mile radius of the natural gas storage facility were relocated. As a result of this leak event, the Porter Ranch Community Air Monitoring Project (PRCAMP) was established to detect and notify the community about the air quality.
During the ongoing rupture, local community leaders began working with health officials, regulatory agencies, academia, and industry to design an independent air monitoring program to measure emissions in ambient air at the natural gas storage facility fence-line.
The information from the air monitoring program was presented to the local community via a public access website that alerted the presence of elevated methane concentrations in the ambient air. The air monitoring equipment and public access website continue to provide a critical benefit to adjacent communities as they continue to assess the long-term health impacts of the blowout.
Argos Scientific, Inc. has over 30 years of experience specializing in air quality management, environmental permitting and compliance, leak detection, and ambient air monitoring. Argos has additional experience in issued complex and multi-stakeholder environments and extensive experience in providing strategic development and technical support with air quality environmental litigation matters.
Part of Argos' innovative approaches include identifying, developing cost-effective strategies to determine risks, educating target audiences, and communicating this information to the public. Argos' passion for safe air quality drives motivation to support the community of Porter Ranch, California through the PRCAMP.
Argos is currently working all over the world, with partnerships in Oregon, California, Colorado, South Africa, and the Middle East.
Visit our website here.
For air quality related issues, please call 1-800-CUT-SMOG.
For any issue related to the operations of any of the fence-line systems or monitoring station, please contact Argos:
PorterRanch@argos-sci.co.za
+1 (503) 421-0228
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